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Table 1 Several common glycoalkaloids identified in potatoes

From: Potato steroidal glycoalkaloids: properties, biosynthesis, regulation and genetic manipulation

Name

CAS accession number

PubChem CID

Glycosidic unit

Molecular formula

Chemical

structure components

First reported

species donor

α-Chaconine

20562-03-2

442,971

β-Chacotriose

C45H73NO14

Solanidine + glucose + rhamnose + rhamnose

S. chacoense

α-Solamarine

20318-30-3

70,680,623

β-Solatriose

C45H73NO16

Tomatidenol + galactose + glucose + rhamnose

S. tuberosum L. var Kennebec

α-Solanine

20562-02-1

9,549,171

β-Solatriose

C45H73NO15

Solanidine + galactose + glucose + rhamnose

S. nigrum

α-Tomatine

17406-45-0

5513

β-Lycotetrose

C50H83NO21

Tomatidine + glucose + glucose + galactose + xylose

S. lycopersicum

β-Chaconine

472-51-5

119,393

β-Chacobiose

C39H63NO10

Solanidine + glucose + rhamnose

 

β-Solamarine

3671-38-3

168,971

β-Chacotriose

C45H73NO15

Tomatidenol + glucose + rhamnose + rhamnose

S. tuberosum L. var Kennebec

β-Solanine

61877-94-9

45,479,590

β-Solabiose

C39H63NO11

Solanidine + galactose + glucose

 

γ-Chaconine

511-36-4

21,123,844

Glucose

C33H53NO6

Solanidine + glucose

 

γ-Solanine

511-37-5

20,841,681

Galactose

C33H53NO6

Solanidine + galactose

 

Commersonine

60776-42-3

185,997

β-Commertetraose

C51H85NO21

Demissidine + galactose + glucose + glucose + glucose

S. commersonii

Dehydrocommersonine

65428-74-2

101,699,426

Î’-Commertetraose

C51H83NO21

Solanidine + galactose + glucose + glucose + glucose

S. commersonii

Dehydrodemissine

195433-57-9

131,751,363

β-Lycotetraose

C50H81NO20

Solanidine + galactose + glucose + glucose + xylose

S. commersonii

Demissine

6077-69-6

442,975

β-Lycotetraose

C50H83NO20

Demissidine + galactose + glucose + glucose + xylose

S. chacoense

Leptine I

101030-83-5

180,940

β-Chacotriose

C47H75NO16

O(23)-Acetylleptinidine + glucose + rhamnose + rhamnose

S. chacoense

Leptine II

101054-39-1

101,699,888

β-Solatriose

C47H75NO17

O(23)-Acetylleptinidine + galactose + glucose + rhamnose

S. chacoense

Leptinine I

101009-59-0

101,699,423

β-Chacotriose

C45H73NO15

Leptinidine + glucose + rhamnose + rhamnose

S. chacoense

Leptinine II

100994-57-8

101,699,425

β-Solatriose

C45H73NO16

Leptinidine + galactose + glucose + rhamnose

S. chacoense

Solamargine

20311-51-7

73,611

β-Chacotriose

C45H73NO15

Solasodine + glucose + rhamnose + rhamnose

S. berthaultii

Solasonine

19121-58-5

119,247

β-Solatriose

C45H73NO16

Solasodine + galactose + mannose + glucose

S. berthaultii